CobaltMaghrebV1, Main, Exploration, bibRecord, 000161

Crystal structure of alluaudite-type Na4Co(MoO4)3

Identifieur interne : 000161 ( Main/Exploration ); précédent : 000160; suivant : 000162

Crystal structure of alluaudite-type Na4Co(MoO4)3

Auteurs : Rawia Nasri [Tunisie] ; Noura Fakhar Bourguiba [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.

RBID : PMC:4186203

Abstract

The title compound, tetrasodium cobalt(II) tris[molybdate(IV)], was prepared by solid-state reactions. The structure is isotypic with Na₃In₂(AsO₄)₃ and Na₃In₂(PO₄)₃. The main structural feature is the presence of infinite chains of edge-sharing X₂O₁₀ (X = Co/Na) dimers, which are linked by MoO₄ tetrahedra, forming a three-dimensional framework enclosing two types of hexagonal tunnels in which Na⁺ cations reside. In this alluaudite structure, Co and Na atoms are located at the same general site with occupancies of 0.503 (5) and 0.497 (6), respectively. The other three Na and one of the two Mo atoms lie on special positions (site symmetries 2, -1, 2 and 2, respectively). The structure is compared with similar structures and other members of alluaudite family.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186203

DOI: 10.1107/S1600536814016729
PubMed: 25309171
PubMed Central: 4186203

Affiliations:

Tunisie

Le document en format XML

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Co(MoO<sub>4</sub>
)<sub>3</sub>
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Co(MoO<sub>4</sub>
)<sub>3</sub>
</title>
<author><name sortKey="Nasri, Rawia" sort="Nasri, Rawia" uniqKey="Nasri R" first="Rawia" last="Nasri">Rawia Nasri</name>
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<country xml:lang="fr">Tunisie</country>
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<author><name sortKey="Fakhar Bourguiba, Noura" sort="Fakhar Bourguiba, Noura" uniqKey="Fakhar Bourguiba N" first="Noura" last="Fakhar Bourguiba">Noura Fakhar Bourguiba</name>
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</nlm:aff>
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<front><div type="abstract" xml:lang="en"><p>The title compound, tetrasodium cobalt(II) tris[molybdate(IV)], was prepared by solid-state reactions. The structure is isotypic with Na<sub>3</sub>
In<sub>2</sub>
(AsO<sub>4</sub>
)<sub>3</sub>
 and Na<sub>3</sub>
In<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
. The main structural feature is the presence of infinite chains of edge-sharing <italic>X</italic>
<sub>2</sub>
O<sub>10</sub>
 (<italic>X</italic>
 = Co/Na) dimers, which are linked by MoO<sub>4</sub>
 tetrahedra, forming a three-dimensional framework enclosing two types of hexagonal tunnels in which Na<sup>+</sup>
 cations reside. In this alluaudite structure, Co and Na atoms are located at the same general site with occupancies of 0.503 (5) and 0.497 (6), respectively. The other three Na and one of the two Mo atoms lie on special positions (site symmetries 2, -1, 2 and 2, respectively). The structure is compared with similar structures and other members of alluaudite family.</p>
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Serveur d'exploration sur le cobalt au Maghreb

Crystal structure of alluaudite-type Na4Co(MoO4)3

Crystal structure of alluaudite-type Na4Co(MoO4)3

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Abstract

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